Volume 7, Issue 2, August 2014, Pages 674–682
Rachid Hsissou1, Y. EL RHAYAM2, and Ahmed Elharfi3
1 Laboratory of Polymers, Radiation and Environment (LPRE), Team of Macromolecular & Organic Chemistry (TMOC), Ibn Tofail University, Faculty of Sciences, Kénitra, Morocco
2 Laboratoire de Chimie Organique & Macromoléculaire, Département de Chimie, Faculté des Sciences, Université Ibn Tofail, B.P. 133, 14000 Kenitra, Maroc
3 Laboratory of Polymers, Radiation and Environment- Team of Macromolecular & Organic Chemistry, Ibn Tofail University, Faculty of sciences, Kenitra, Morocco
Original language: English
Copyright © 2014 ISSR Journals. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
In this work we have synthesized a new bifunctional epoxy resin namely diglycidyl 3-aminopropyl triethylsilane (DGAPTES).
This resin was synthesized in two steps: the first one is condensing the epichlorohydrin with 3-aminopropyl triethylsilane; the second is introducing the calcium carbonate as a base to form the oxirane cycle.
The resin obtained was characterized by infrared Fourier transformation spectroscopy (FTIR), its chemical structure was also confirmed by the nuclear magnetic resonance of 1H and proton and carbon 13C (1H NMR and 13C NMR) on the one hand, and we have improved the thermal properties of the standard resin (DGEBA) by adding an amount of (DGAPTES) as an organic load in the standard matrix, on the other hand. This formulation has been studied by thermogravimetry as a macroscopic approach. The uptake of humidity of the standard DGAPTES and the crosslinked DGEBA/DGAPTES/MDA according to 80%/20%/traces was studied in order to improve the Fickien behavior.
Author Keywords: DGEBA, DGAPTES, formulation, thermogravimetry and humidity uptake.
Rachid Hsissou1, Y. EL RHAYAM2, and Ahmed Elharfi3
1 Laboratory of Polymers, Radiation and Environment (LPRE), Team of Macromolecular & Organic Chemistry (TMOC), Ibn Tofail University, Faculty of Sciences, Kénitra, Morocco
2 Laboratoire de Chimie Organique & Macromoléculaire, Département de Chimie, Faculté des Sciences, Université Ibn Tofail, B.P. 133, 14000 Kenitra, Maroc
3 Laboratory of Polymers, Radiation and Environment- Team of Macromolecular & Organic Chemistry, Ibn Tofail University, Faculty of sciences, Kenitra, Morocco
Original language: English
Copyright © 2014 ISSR Journals. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract
In this work we have synthesized a new bifunctional epoxy resin namely diglycidyl 3-aminopropyl triethylsilane (DGAPTES).
This resin was synthesized in two steps: the first one is condensing the epichlorohydrin with 3-aminopropyl triethylsilane; the second is introducing the calcium carbonate as a base to form the oxirane cycle.
The resin obtained was characterized by infrared Fourier transformation spectroscopy (FTIR), its chemical structure was also confirmed by the nuclear magnetic resonance of 1H and proton and carbon 13C (1H NMR and 13C NMR) on the one hand, and we have improved the thermal properties of the standard resin (DGEBA) by adding an amount of (DGAPTES) as an organic load in the standard matrix, on the other hand. This formulation has been studied by thermogravimetry as a macroscopic approach. The uptake of humidity of the standard DGAPTES and the crosslinked DGEBA/DGAPTES/MDA according to 80%/20%/traces was studied in order to improve the Fickien behavior.
Author Keywords: DGEBA, DGAPTES, formulation, thermogravimetry and humidity uptake.
How to Cite this Article
Rachid Hsissou, Y. EL RHAYAM, and Ahmed Elharfi, “Synthesis and characterization of a new epoxy resin homologous to DGEBA (diglycidyl 3-Aminopropyl Triethyl Silane): a study of thermal properties,” International Journal of Innovation and Applied Studies, vol. 7, no. 2, pp. 674–682, August 2014.
