A new Asymmetric synthesis of triazacyclohexanes compound were prepared from the mixed two equivalents of 4-fluorobenzylamine and one equivalent tert-butylamine or two equivalents 4-bromoaniline and one equivalent isobutylamine with three equivalents of formaldehyde, gave solids compounds with good yields of 1,3-bis(4-fluorobenzyl)-5-tert-butyl-1,3,5- triazacyclohexane 1,3-bis(4-bromophenyl)-5-isobutyl-1,3,5- triazacyclohexane.
The identification of these compounds has been done by CCM, infrared spectroscopy IR, nuclear magnetic resonance spectroscopy of 1H-NMR, 13C NMR.