The present study aims at analysing the appropriation of Information and Communication Technology (ICT) by the women association (WA) for processing of shea nuts into shea butter and other by-products in the municipality of Ouessè in central Benin. To achieve this, individual as well as focus groups interviews were used to collect data from the 30 members of this association. In addition, the method of “grading” based on weighted indices was used to analyse the preponderance of ICT uses and their appropriation factors. The results showed that telephone was the dominant ICT used within the WA, and that the transmission of information among members, the search for market information, the advertisements of products, the connection with technical and commercial partners and the restitution of training sessions were the most frequent uses of ICT within this women association. Our study revealed also that appropriation of the ICT has generated for the WA some positive effects in terms of time saving, financial gains, better understanding of information, reliability of information, improvement of product packaging and display, regularity of members to meetings, maintenance of social relations among members, and improvement of their relations with the partners. It appears from these results that appropriation of ICT could contribute to considerably improving the organisation and socioeconomic performances of women associations that were rather, and most often, marginalized in the access to and use of new technologies in rural areas.