Volume 26, Issue 4, July 2019, Pages 1084–1088
L. Lefrada1, R. D. Köhn2, A. Bouchemma3, F. Schaper4, and S. Malki5
1 Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi, Algeria
2 Departement of Chemistry University of Bath, Bath, BA2 7AY, United Kingdom
3 Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi, Algeria
4 Laboratoire du Frank Schaper, Département de chimie, Faculté des arts et des sciences, Université de Montréal, Canada
5 Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi, Algeria
Original language: English
Copyright © 2019 ISSR Journals. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
A new Asymmetric synthesis of triazacyclohexanes compound were prepared from the mixed two equivalents of 4-fluorobenzylamine and one equivalent tert-butylamine or two equivalents 4-bromoaniline and one equivalent isobutylamine with three equivalents of formaldehyde, gave solids compounds with good yields of 1,3-bis(4-fluorobenzyl)-5-tert-butyl-1,3,5- triazacyclohexane 1,3-bis(4-bromophenyl)-5-isobutyl-1,3,5- triazacyclohexane. The identification of these compounds has been done by CCM, infrared spectroscopy IR, nuclear magnetic resonance spectroscopy of 1H-NMR, 13C NMR.
Author Keywords: Triazacyclohexane, asymmetric, 4-fluorobenzylamine, tert-butylamine.
L. Lefrada1, R. D. Köhn2, A. Bouchemma3, F. Schaper4, and S. Malki5
1 Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi, Algeria
2 Departement of Chemistry University of Bath, Bath, BA2 7AY, United Kingdom
3 Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi, Algeria
4 Laboratoire du Frank Schaper, Département de chimie, Faculté des arts et des sciences, Université de Montréal, Canada
5 Département Sciences de la Matière, Faculté des Sciences Exactes et Sciences de la Nature et de la Vie, Université Oum El Bouaghi, Algeria
Original language: English
Copyright © 2019 ISSR Journals. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Abstract
A new Asymmetric synthesis of triazacyclohexanes compound were prepared from the mixed two equivalents of 4-fluorobenzylamine and one equivalent tert-butylamine or two equivalents 4-bromoaniline and one equivalent isobutylamine with three equivalents of formaldehyde, gave solids compounds with good yields of 1,3-bis(4-fluorobenzyl)-5-tert-butyl-1,3,5- triazacyclohexane 1,3-bis(4-bromophenyl)-5-isobutyl-1,3,5- triazacyclohexane. The identification of these compounds has been done by CCM, infrared spectroscopy IR, nuclear magnetic resonance spectroscopy of 1H-NMR, 13C NMR.
Author Keywords: Triazacyclohexane, asymmetric, 4-fluorobenzylamine, tert-butylamine.
How to Cite this Article
L. Lefrada, R. D. Köhn, A. Bouchemma, F. Schaper, and S. Malki, “SYNTHESIS AND CHARACTERISATON OF NEW ASYMMETRIC TRIAZACYCLOHEXANES COMPOUNDS,” International Journal of Innovation and Applied Studies, vol. 26, no. 4, pp. 1084–1088, July 2019.
